[(Z)-O-Ethyl N-(4-chloro­phen­yl)thio­carbamato-κS](triphenyl­phosphine-κP)gold(I) dichloro­methane hemisolvate

نویسندگان

  • Primjira P. Tadbuppa
  • Edward R. T. Tiekink
چکیده

The Au(I) atom in the title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)]·0.5CH(2)Cl(2), exists within a slightly distorted linear geometry defined by an S,P donor set [S-Au-P angle = 178.01 (4)°]; a close intra-molecular Au⋯O contact [2.964 (4) Å] also occurs. In the crystal structure, mol-ecules are linked into supra-molecular chains propagating along [010] by C-H⋯N, C-H⋯S and C-H⋯π inter-actions. The solvent mol-ecule is disordered about a twofold rotation axis.

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[(Z)-O-Ethyl N-(4-nitro­phen­yl)thio­carbamato-κS](triphenyl­phosphine-κP)gold(I) dichloro­methane solvate

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[(Z)-O-Ethyl-N-(o-tol­yl)thio­carbamato-κS](triphenyl­phosphine-κP)gold(I)

The title compound, [Au(C(10)H(12)NOS)(C(18)H(15)P)], features a linear geometry for the Au atom defined by the S and P donor atoms. A small deviation from the ideal geometry is noted and is ascribed to an intra-molecular Au⋯O contact [2.936 (4) Å]. Inversion dimers are formed in the crystal structure mediated by C-H⋯π inter-actions between centrosymmetrically related o-tolyl residues [C⋯Cg = 3...

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[(Z)-N-(2-Chloro­phen­yl)-O-ethyl­thio­carbamato-κS](triphenyl­phosphine-κP)gold(I)

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عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010